刘志敏
刘志敏,中国科学院化学研究所研究员,课题组长。
人物经历
1997年在中国石油大学(北京)获博士学位; 1997年9月至1999年8月在中国科学院化学研究所做博士后研究,出站后留该所工作,晋升为副研究员;2007年被聘为研究员,课题组长。
主要成果
长期从事与超临界流体、离子液体等绿色介质相关的研究, 相继在绿色溶剂的性质研究和利用绿色溶剂制备功能材料等方面开展了系统工作。近年来,研究方向主要集中在用绿色溶剂构筑化学功能材料的研究,提出了多种利用绿色溶剂合成功能材料的新方法,在功能材料的绿色合成方面开展了一系列有特色的工作。在国内外主要刊物上共发表SCI收录论文170余篇,其中在Adv. Mater、J. Am. Chem. Soc.、Angew. Chem. Int. Ed、Adv. Fun. Mater. 等影响因子3.0以上期刊上发表论文80多篇,论文被他人引用700余次;申请和获授权国家发明专利19项;多次在国际学术会议上作邀请报告。
主要论文与著作
论文
[1] Chang, Xiaoqian, Wang, Yuepeng, Zhao, Yanfei, Wang, Ying, Li, Rongxiang, Ke, Zhengang, Chen, Penglei, Liu, Zhimin. 氢 bonding-catalyzed synthesis of 1,4-dioxanes from dehydrative cyclization of vicinal diols in ionic liquids. NEW JOURNAL OF 化学[J]. 2023, 47(15): 7299-7304.
[2] Li, Rongxiang, Zeng, Wei, Zhao, Runyao, Zhao, Yanfei, Wang, Yuepeng, Zhang, Fengtao, Tang, Minhao, Wang, Ying, Chang, Xiaoqian, Wu, Fengtian, Liu, Zhimin. TiO2 nanoparticle supported Ru catalyst for chemical upcycling of 聚乙烯 terephthalate to alkanes. NANO RESEARCH[J]. 2023.
[3] Zhimin Liu. Cation-Anion Confined 氢Bonding Catalysis Strategy for Ring-Closing C-O/O-H Metathesis of Alkoxy Alcohols to O-heterocycles. Green Chem.[J]. 2023, 25: 8791 -8797.
[4] Wang, Ying, Zeng, Wei, Zhao, Yanfei, Tang, Minhao, Chang, Xiaoqian, Xu, Yueting, Li, Rongxiang, Liu, Zhimin, Zhimin Liu. 纤维素Phytic Acid Composite Complexed Ru Catalyst for CO2 Hydrogenation to Free Formic Acid. CHEMCATCHEM[J]. 2023, 15(2): e202201168-.
[5] liuzm.Temporally separated CO2 photoreduction and H2O photooxidation over redox-active conjugated organic 均聚物 films,. CCS Chem.[J]. 2023.
[6] liuzm.Partially Nitrided Ni Nanoclusters Achieve 能量Efficient Electrocatalytic CO2 Reduction to CO at Ultralow Overpotential. 2023, DOI: 10.1002/adma.202205262.
[7] liuzm.氢Bonding Mediated N-alkylation of Amine with Alcohol via 氢气 Autotransfer over 钴 Catalyst. ChemSusChem[J]. 2023.
[8] Wu, Fengtian, Wang, Yuepeng, Zhao, Yanfei, Tang, Minhao, Zeng, Wei, Wang, Ying, Chang, Xiaoqian, Xiang, Junfeng, Han, Buxing, Liu, Zhimin. Lactate anion catalyzes aminolysis of polyesters with anilines. SCIENCE ADVANCES[J]. 2023, 9(5): eade7971.
[9] Wu, Fengtian, Zhao, Yanfei, Wang, Yuepeng, Xu, Yueting, Tang, Minhao, Wang, Zhenpeng, Han, Buxing, Liu, Zhimin. 氢bonding and acid cooperative catalysis for benzylation of arenes with benzyl alcohols over ionic 羧基液体丁腈橡胶s. GREEN 化学[J]. 2022, 24(8): 3137-3142.
[10] Ye, Wenqiang, Wang, Yuepeng, Ji, Guipeng, Zhang, Fengtao, Zhao, Yanfei, Liu, Zhimin. Carbazolic Conjugated Organic Polymers for visibleLight-Driven CO2 Photoreduction with H2O to CO with High Efficiency and Selectivity. CHEMSUSCHEM[J]. 2022, 15(16).
[11] 李荣香, 赵燕飞, 刘志敏. 离子液体反应体系的氢键作用. 中国科学(化学). 2022, 52(5): 655-667.
[12] Guipeng Ji, Yanfei Zhao, Zhimin Liu. 设计 of porous organic 均聚物 catalysts for transformation of 碳 dioxide. 绿色化学工程(英文)[J]. 2022, 3(2): 96-110.
[13] liuzm.Fengtao Zhang, Peng Wang, Runyao Zhao, Yiding Wang, Jianji Wang, Buxing Han, Zhimin Liu*,. Tuning d-Band Structure of CuII in Coordinated Polymer via d–π Conjugation for Improving CO2 Electroreduction Selectivity toward C2 Products,. chemsuschem[J]. 2022, 15: e202201267.
[14] 赵燕飞, 刘志敏. 离子液体调控化学反应研究进展,.《中国科学,化学》[J]. 2021.
[15] Zhao, Yanfei, Han, Buxing, Liu, Zhimin. Ionic-羧基液体丁腈橡胶-Catalyzed Approaches under Metal-Free Conditions. ACCOUNTS OF CHEMICAL RESEARCHnull. 2021, 54(16): 3172-3190.
[16] Li, Ruipeng, Wang, Yuepeng, Zhao, Yanfei, Zhang, Fengtao, Zeng, Wei, Tang, Minhao, Xiang, Junfeng, Zhang, Xiaoyu, Han, Buxing, Liu, Zhimin. Hydrogen-Bonding-Mediated Selective Hydrogenation of Aromatic Ketones over Pd/C in Ionic 羧基液体丁腈橡胶s at Room 温度. ACS SUSTAINABLE 化学 \u0026 ENGINEERING[J]. 2021, 9(42): 14216-14223.
[17] Wang, Huan, Zhao, Yanfei, Zhang, Fengtao, Ke, Zhengang, Han, Buxing, Xiang, Junfeng, Wang, Zhenpeng, Liu, Zhimin. 氢bond donor and acceptor cooperative catalysis strategy for cyclic dehydration of diols to access O-heterocycles. SCIENCE ADVANCES[J]. 2021, 7(22).
[18] Xu, Yueting, Zhao, Yanfei, Zhang, Fengtao, Wang, Yuepeng, Li, Ruipeng, Xiang, Junfeng, Liu, Zhimin. 氢 bonding-catalysed alcoholysis of propylene 氧化物 at room 温度 CHEMICAL COMMUNICATIONS[J]. 2021, 57(70): 8734-8737.
[19] liuzm.Ruipeng Li, Yanfei Zhao*, Huan Wang, Dongyang Li, Yunyan Wu, Hongye Zhang, Minhao Tang, and Zhimin Liu*, Ionic 羧基液体丁腈橡胶-promoted formylation of N(sp2)-heteroarenes with CO2/H2 over Pd/C. ACS Sustainable Chem. Eng.[J]. 2021, 44(9): 2507-2514.
[20] Fan Wen, Fengtao Zhang, Zhen Wang, Xiaoxiao Yu, Guipeng Ji, Dongyang Li, Shengrui Tong, Yingbin Wang, Buxing Han, Zhimin Liu. 酰胺bridged conjugated organic polymers: efficient metal-free catalysts for visiblelight-driven CO2 reduction with H2O to CO. CHEMICAL SCIENCE[J]. 2021, 12(34): 11548-11553.
[21] liuzm.Alcohol Promoted N-methylation of Anilines with CO2/H2 over 钴 Catalyst under Mild Conditions. Green Chem.. 2021.
[22] Wu, Yunyan, Zhao, Yanfei, Wang, Huan, Zhang, Fengtao, Li, Ruipeng, Xiang, Junfeng, Wang, Zhenpeng, Han, Buxing, Liu, Zhimin. Ambient reductive synthesis of N-heterocyclic compounds over 纤维素derived 碳 supported Pt nanocatalyst under H(2)atmosphere GREEN 化学[J]. 2020, 22(12): 3820-3826.
[23] liuzm.Carbon Nitride-Based Single-Atom Cu Catalyst for Highly Efficient Carboxylation of Alkynes with Atmospheric CO2,. Ind. Eng. Chem. Res.. 2020.
[24] Zhengang Ke, Bo Yu, Yunyan Wu, Yanfei Zhao, Peng Yang, Shien Guo, Zhimin Liu. A Novel Route to Synthesize N,N-Dimethyl Arylmethylamines from Aryl 醛基s, 乌洛托品 and 氢 中国化学:英文版[J]. 2020, 38(8): 842-846.
[25] Wu, Yunyan, 左姓, Shouwei, Zhao, Yanfei, Wang, Huan, Li, Dongyang, Guo, Shien, Zhao, Zhijuan, Zhang, Jing, Han, Buxing, Liu, Zhimin. Biomass-derived metal-organic hybrids for CO2 transformation under ambient conditions. GREEN 化学[J]. 2020, 22(9): 2846-2851.
[26] Yu, Xiaoxiao, Wen, Fan, Zhang, Fengtao, Yang, Peng, Zhao, Yanfei, Wu, Yunyan, Wang, Yingbin, Liu, Zhimin. Photo催化 Reduction of CO(2)to CO over Quinacridone/BiVO(4)Nanocomposites. CHEMSUSCHEM[J]. 2020, 13(20): 5565-5570.
[27] liuzm.Photosensitive Hypercrosslinked polymers derived from 3D ring-like arenes: Promising catalysts for singlet-氧 generation,. ACS Sustainable Chem. Eng.. 2020.
[28] 吴云雁, 赵燕飞, 李瑞鹏, 王欢, 刘志敏. 离子液体促进Ru/C催化有机胺与CO2/H2氮甲酰化反应研究. 中国科学:化学[J]. 2020, 299-305.
[29] Guo, Shien, Yang, Peng, Zhao, Yanfei, Yu, Xiaoxiao, Wu, Yunyan, Zhang, Hongye, Yu, Bo, Han, Buxing, George, Michael W, Liu, Zhimin. Direct Z-Scheme Heterojunction of SnS2/硫Bridged Covalent 三嗪 Frameworks for visibleLight-Driven CO2 Photoreduction. CHEMSUSCHEM[J]. 2020, 13(23): 6278-6283.
[30] Ma, Zhishuang, Yang, Zhenzhen, Zhang, Hongye, Liu, Zhimin. 氮-doped microporous 碳 materials with uniform pore diameters: 设计 and applications in CO2 and H-2 吸附. MICROPOROUS AND MESOPOROUS MATERIALS[J]. 2020, 296.
[31] liuzm.Photoreduction of CO2 to CH4 under visibleLight Irradiation Using Multiple-Site Ionic 羧基液体丁腈橡胶 as Absorbent and Photosensitizer,. ACS Sustainable Chem. Eng.. 2020.
[32] 王欢, 吴云雁, 赵燕飞, 刘志敏. 离子液体介导CO2化学转化研究进展. 物理化学学报[J]. 2020, 37(5): 157-168.
[33] Wang, Huan, Zhao, Yanfei, Zhang, Fengtao, Wu, Yunyan, Li, Ruipeng, Xiang, Junfeng, Wang, Zhenpeng, Han, Buxing, Liu, Zhimin. 氢Bonding Catalyzed Ring-Closing C-O/C-O Metathesis of Aliphatic Ethers over Ionic Liquid under Metal-Free Conditions. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2020, 59(29): 11850-11855.
[34] liuzm.Photocatalytic Reduction of CO2 over Reduced Graphene 氧化物 Supported Quinacridone Nanoparticles. Ind. Eng. Chem. Res.. 2019.
[35] Liu, Zhenghui, Yang, Zhenzhen, Wang, Peng, Yu, Xiaoxiao, Wu, Yunyan, Wang, Huan, Liu, Zhimin. Co-catalyzed Hydrogenation of Levulinic Acid to gamma-Valerolactone under Atmospheric 压强. ACS SUSTAINABLE 化学 \u0026 ENGINEERING[J]. 2019, 7(22): 18236-18241.
[36] Wang, Huan, Zhao, Yanfei, Wu, Yunyan, Li, Ruipeng, Zhang, Hongye, Yu, Bo, Zhang, Fengtao, Xiang, Junfeng, Wang, Zhenpeng, Liu, Zhimin. Hydrogenation of 碳 Dioxide to C-2-C-4 Hydrocarbons Catalyzed by Pd(PtBu3)(2)-氯化亚铁 with Ionic 羧基液体丁腈橡胶 as Cocatalyst. CHEMSUSCHEM[J]. 2019, 12(19): 4390-4394.
[37] Zhang, Fengtao, Zhang, Hongye, Liu, Zhimin. Recent advances in electrochemical reduction of CO2. CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY[J]. 2019, 16: 77-84.
[38] liuzm.Selective Synthesis of Formamides, 1,2-胺醚(N-heterocyclic)ethanes and Methylamines from Cyclic Amines and CO2/H2 Catalyzed by Ionic 羧基液体丁腈橡胶-Pd/C system. Chem. Sci.. 2019.
[39] liuzm. Eosin Y-Functionalized Conjugated Organic 均聚物s for Visible-Light Driven CO2 Reduction to CO. Angew. Chem. Int. Ed.. 2019.
[40] liuzm.Ionic Liquid Promoted CO2 Hydrogenation to Free Formic Acid catalyzed by Pd/C. Ind. Eng. Chem. Res.. 2019.
[41] Yu, Xiaoxiao, Yang, Zhenzhen, Zhang, Fengtao, Liu, Zhenghui, Yang, Peng, Zhang, Hongye, Yu, Bo, Zhao, Yanfei, Liu, Zhimin. A rose bengal-函数alized porous organic polymer for carboxylative cyclization of propargyl alcohols with CO2. CHEMICAL COMMUNICATIONS[J]. 2019, 55(83): 12475-12478.
[42] Ke, Zhengang, Yu, Bo, Wang, Huan, Xiang, Junfeng, Han, Juanjuan, Wu, Yunyan, Liu, Zhenghui, Yang, Peng, Liu, Zhimin. 钴catalyzed synthesis of N-containing heterocycles via cyclization of ortho-substituted anilines with CO2/H-2. GREEN 化学[J]. 2019, 21(7): 1695-1701.
[43] Wang, Huan, Zhao, Yanfei, Ke, Zhengang, Yu, Bo, Li, Ruipeng, Wu, Yunyan, Wang, Zhenpeng, Han, Juanjuan, Liu, Zhimin. Synthesis of renewable acetic acid from CO2 and lignin over an ionic 羧基液体丁腈橡胶-based catalytic system. CHEMICAL COMMUNICATIONS[J]. 2019, 55(21): 3069-3072.
[44] liuzm.Porous Nitrogen Deficient Graphitic 碳 Nitride Nanotubes with Tunable Band Structures for Efficient CO2 Photoreduction. Catal. Sci \u0026 Tech.2019.
[45] liuzm.Mesoporous 亚胺Based Organic Polymers: Catalyst-Free Synthesis in H₂O and Application in CO2 Conversion. Chem. Commun.. 2018.
[46] Liu, Xinwei, Zhang, Hongye, Wu, Cailing, Liu, Zhenghui, Chen, Yu, Yu, Bo, Liu, Zhimin. 铜catalyzed synthesis of benzanilides from lignin model substrates 2-phenoxyacetophenones under an air atmosphere NEW JOURNAL OF 化学[J]. 2018, 42(2): 1223-1227.
[47] Guo, Shien, Zhang, Hongye, Chen, Yu, Liu, Zhenghui, Yu, Bo, Zhao, Yanfei, Yang, Zhenzhen, Han, Buxing, Liu, Zhimin. Visible-Light-Driven Photoreduction of CO2 to CH4 over N,O,P-Containing Covalent Organic Polymer Submicrospheres. ACS CATALYSIS[J]. 2018, 8(5): 4576-4581.
[48] Xiaoying Luo, Hongye Zhang, Zhengang Ke, Cailing Wu, Shien Guo, Yunyan Wu, Bo Yu, Zhimin Liu. N-doped 碳 supported Pd catalysts for N-formylation of amines with CO2/H2. 中国科学:化学英文版[J]. 2018, 725-731.
[49] Liu, Zhenghui, Yang, Zhenzhen, Ke, Zhengang, Yu, Xiaoxiao, Zhang, Hongye, Yu, Bo, Zhao, Yanfei, Liu, Zhimin. 乙醇mediated N-formylation of amines with CO2/H-2 over 钴 catalysts. NEW JOURNAL OF 化学[J]. 2018, 42(16): 13933-13937.
[50] Liu, Zhenghui, Yang, Zhenzhen, Yu, Bo, Yu, Xiaoxiao, Zhang, Hongye, Zhao, Yanfei, Yang, Peng, Liu, Zhimin. 铑Catalyzed Formylation of Aryl Halides with CO2 and H-2. ORGANIC LETTERS[J]. 2018, 20(17): 5130-5134.
[51] liuzm.Recent Advances in Photocatalytic CO2 Reduction Using 地球abundant Metal Complexes-derived photocatalyst. Chin. J. Chem.2018.
[52] liuzm.Shien Guo, Yunyan Wu, Zhimin Liu, 钴catalyzed Synthesis of Unsymmetrically N, N-Disubstituted Formamides via Reductive Coupling of Primary Amines and Aldehydes with CO2 and H2. ORGANICLETT. 2018.
[53] Bo Yu, Peng Yang, Xiang Gao, Zhenzhen Yang, Yanfei Zhao, Hongye Zhang, Zhimin Liu. Sequential protocol for C(sp)-H carboxylation with CO2:KO^tBu-catalyzed C(sp)-H silylation and KO^tBu-mediated carboxylation. 中国科学化学英文版[J]. 2018, 61(4): 449-456.
[54] Wu, Yunyan, Zhao, Yanfei, Li, Ruipeng, Yu, Bo, Chen, Yu, Liu, Xinwei, Wu, Cailing, Luo, Xiaoying, Liu, Zhimin. Tetrabutylphosphonium-Based Ionic Liquid Catalyzed CO2 Transformation at Ambient Conditions: A Case of Synthesis of alpha-Alkylidene Cyclic Carbonates. ACS CATALYSIS[J]. 2017, 7(9): 6251-6255.
[55] Chen, Yu, Ji, Guipeng, Guo, Shien, Yu, Bo, Zhao, Yanfei, Wu, Yunyan, Zhang, Hongye, Liu, Zhenghui, Han, Buxing, Liu, Zhimin. Visible-light-driven conversion of CO2 from air to CO using an ionic liquid and a conjugated 均聚物 GREEN 化学[J]. 2017, 19(24): 5777-5781.
[56] liuzm. 聚脲 derived from CO2 and diamines: highly efficient catalysts for C-H arylation of benzene. New J. Chem.2017.
[57] liuzm.Zhenghui Liu, Zhenzhen Yang, Xiaoxiao Yu, Guipeng Ji, Hongye Zhang, Bo Yu, Yanfei Zhao and Zhimin Liu*, Highly Efficient 钴Catalyzed Methylation of Amines and C-H Bonds in Indoles Using 甲醇 Adv. Catal. Syn.. 2017.
[58] Yang, Zhenzhen, Wang, Huan, Ji, Guipeng, Yu, Xiaoxiao, Chen, Yu, Liu, Xinwei, Wu, Cailing, Liu, Zhimin. 吡啶functionalized organic porous polymers: applications in efficient CO2 adsorption and conversion. NEW JOURNAL OF 化学[J]. 2017, 41(8): 2869-2872.
[59] liuzm.Lewis Acid-catalyzed Reductive Amination/Cyclization of Levulinic Acid to Pyrrolidones versus Pyrrolidines under Mild Conditions. Green Chem.. 2017.
[60] Wu, Cailing, Zhang, Hongye, Yu, Bo, Chen, Yu, Ke, Zhengang, Guo, Shien, Liu, Zhimin. Lactate-Based Ionic Liquid Catalyzed Reductive Amination/Cyclization of Keto Acids under Mild Conditions: A Metal-Free Route To Synthesize Lactams. ACS CATALYSIS[J]. 2017, 7(11): 7772-7776.
[61] Yu, Xiaoxiao, Yang, Zhenzhen, Zhang, Hongye, Yu, Bo, Zhao, Yanfei, Liu, Zhenghui, Ji, Guipeng, Liu, Zhimin. Ionic liquid/H2O-mediated synthesis of mesoporous organic polymers and their application in methylation of amines. CHEMICAL COMMUNICATIONS[J]. 2017, 53(44): 5962-5965.
[62] Liu, Zhenghui, Yang, Zhenzhen, Yu, Xiaoxiao, Zhang, Hongye, Yu, Bo, Zhao, Yanfei, Liu, Zhimin. Methylation of C(sp(3))-H/C(sp(2))-H Bonds with Methanol Catalyzed by 钴 System. ORGANIC LETTERS[J]. 2017, 19(19): 5228-5231.
[63] Yang, Zhenzhen, Liu, Zhenghui, Zhang, Hongye, Yu, Bo, Zhao, Yanfei, Wang, Huan, Ji, Guipeng, Chen, Yu, Liu, Xinwei, Liu, Zhimin. N-Doped porous carbon nanotubes: synthesis and application in catalysis. CHEMICAL COMMUNICATIONS[J]. 2017, 53(5): 929-932.
[64] Hao, Leiduan, Zhang, Hongye, Luo, Xiaoying, Wu, Cailing, Zhao, Yanfei, Liu, Xinwei, Gao, Xiang, Chen, Yu, Liu, Zhimin. Reductive formylation of amines with CO2 using 钠 borohydride: A catalyst-free route. JOURNALOFCO2UTILIZATION[J]. 2017, 22: 208-211.
[65] Ke, Zhengang, Hao, Leiduan, Gao, Xiang, Zhang, Hongye, Zhao, Yanfei, Yu, Bo, Yang, Zhenzhen, Chen, Yu, Liu, Zhimin. Reductive Coupling of CO2, Primary Amine, and Aldehyde at Room 温度: A Versatile Approach to Unsymmetrically N,N-Disubstituted Formamides. 化学A EUROPEAN JOURNAL[J]. 2017, 23(41): 9721-9725.
[66] Yu, B, Yang, P, Gao, X, Yang, Z Z, Zhao, Y F, Zhang, H Y, Liu, Z M. CsF-promoted carboxylation of aryl(hetaryl) terminal alkynes with atmospheric CO2 at room 温度 NEW JOURNAL OF 化学[J]. 2017, 41(17): 9250-9255.
[67] Ji, Guipeng, Yang, Zhenzhen, Zhang, Hongye, Zhao, Yanfei, Yu, Bo, Ma, Zhishuang, Liu, Zhimin. Hierarchically Mesoporous o-Hydroxyazobenzene Polymers: Synthesis and Their Applications in CO2 Capture and Conversion. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2016, 55(33): 9685-9689.
[68] liuzm.Formylation of Aryl Bromides with CO2 to Aryl Aldehydes. Chem. Eur. J.2016.
[69] Gao, Xiang, Yu, Bo, Yang, Zhenzhen, Zhao, Yanfei, Zhang, Honge, Hao, Leiduan, Han, Buxing, Liu, Zhimin. Ionic 羧基液体丁腈橡胶Catalyzed C-S Bond Construction using CO2 as a C1 Building Block under Mild Conditions: A Metal-Free Route to Synthesis of Benzothiazoles. ACS CATALYSIS[J]. 2015, 5(11): 6648-6652.
[70] liuzm.Task-specific ionic liquid and CO2 cocatalysed efficient hydration of propargylic alcohols to α-hydroxy ketones. Chem. Sci.. 2015, [71] Zhao, Yanfei, Yu, Bo, Yang, Zhenzhen, Zhang, Hongye, Hao, Leiduan, Gao, Xiang, Liu, Zhimin. A Protic Ionic Liquid Catalyzes CO2 Conversion at Atmospheric Pressure and Room Temperature: Synthesis of Quinazoline-2,4-(1H,3H)-diones. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2014, 53(23): 5922-5925.
资料来源:
著作
1.二氧化碳化学转化,科学出版社,2018-10,第1作者
资料来源:
人才培养
刘志敏指导的硕士研究生有罗小颖、徐悦霆、赵润瑶、张会等。她指导的博士研究生有谢芸、陶然婷、纪桂鹏、吴云雁、杨鹏、汪岳鹏、曾伟、王颖、李荣香、王一丁等。
参考资料
刘志敏.中国科学院大学.2024-10-29