王官武
王官武，1966年生于四川富顺，现任中国科学技术大学化学与材料科学学院教授、博士生导师。他是中国科学院"百人计划"入选者和国家杰出青年科学基金获得者。
人物经历
1983-1987，本科，兰州大学化学系
1987-1990，硕士，兰州大学化学系（导师：刘有成院士）
1990-1993，博士，兰州大学化学系（导师：刘有成院士）
1993-1995，复旦大学化学系（吴世晖教授）
1995-1996，京都大学化学研究所（小松弘一教授）
1996-1997，肯塔基大学化学系（Mark S. Meier教授）
1997-1998，芝加哥大学化学系（Philip E. Eaton教授）
1999-2000，耶鲁大学化学系（Martin Saunders院士）
2000- 中国科学技术大学化学与材料科学学院
2001.7-8, 京都大学化学研究所访问教授
主要成就
研究方向
富勒烯化学、绿色化学、计算化学、分子化学
科研项目
中国科学院“引进海外杰出人才”项目，200万元，2000-2003；
国家杰出青年科学基金项目，80万元，2002-2005；
国家自然科学基金重点项目“富勒烯骨架修饰及其应用研究”，300万，2012-2016
获得荣誉
1999年度中国科学院"引进海外杰出人才"计划("百人计划")入选者
2001年度国家杰出青年科学基金获得者
2003年度国家中华人民共和国国家自然科学基金委员会创新研究群体骨干成员
2004年入选国家七部委首批"新世纪百千万人才工程"
2005年获国务院特殊津贴
2005年获第七届安徽省青年科技奖
2007年获“药明康德生命化学研究奖”
社会任职
《科学通报》编委（2002-）、《有机化学》编委（2007-）、《The Open Catalysis Journal》编委（2008-）、《影像科学与光化学》编委（2011-）
个人作品
文章及专著
2007-2012
1. Wang, G.W.; Li, F. B., Transition Metal Salt-Mediated Radical Reactions of 60Fullerene. Current Organic 化学 2012, 16, (9), 1109-1127.
2. Wang, G.W.; Gao, J., Solvent-free bromination reactions with 钠 溴化物 and oxonepromoted by mechanical milling. Green Chemistry 2012, 14, (4), 1125-1131.
3. Su, Y. T.;Wang, Y. L.; Wang, G. W., Palladiumcatalysed heteroannulation of 60 fullerenewith N-benzyl sulfonamides and subsequent functionalisation. Chem Commun 2012,48, (65), 8132-8134.
4. Liu, T.X.; Wei, T.; Zhu, S. E.; Wang, G. W.; Jiao, M. Z.; Yang, S. F.; Bowles, F. L.;Olmstead, M. M.; Balch, A. L., Azide Addition to an EndohedralMetallofullerene: Formation of Azafulleroids of Sc3N@I-h-C-80. J Am Chem Soc2012, 134, (29), 11956-11959.
5. Li, F. B.;You, X.; Wang, G. W., Ferric Perchlorate-Mediated Synthesis of 1,2-FullerenolsC-60(OCOR) (OH). J Org Chem 2012, 77, (15), 6643-6647.
6. Li, F. B.;You, X.; Liu, T. X.; Wang, G. W., Fullerenyl Boronic Esters: FerricPerchlorate-Mediated Synthesis and Functionalization. Org Lett 2012, 14, (7),1800-1803.
7. Li, F.;Liu, T. X.; Wang, G. W., Synthesis of 60 Fullerene-Fused Sultones via SulfonicAcid Group-Directed C-H Bond Activation. Org Lett 2012, 14, (8), 2176-2179.
8. Li, D. D.;Yuan, T. T.; Wang, G. W., 钯Catalyzed Ortho-Arylation of Benzamides viaDirect sp(2) C-H Bond Activation. J Org Chem 2012, 77, (7), 3341-3347.
9. Wang, G.W.; Yuan, T. T.; Li, D. D., One-Pot Formation of C-C and .cn Bonds through钯Catalyzed Dual C-H Activation: Synthesis of Phenanthridinones. AngewChem Int Edit 2011, 50, (6), 1380-1383.
10. Wang, G. W.;Wang, C. Z.; Zou, J. P., Radical Reaction of 60 Fullerene with PhosphorusCompounds Mediated by 锰(III) 乙酸盐 J Org Chem 2011, 76, (15),6088-6094.
11. Wang, G. W.;Wang, C. Z.; Zhu, S. E.; Murata, Y., Manganese(III) acetate-mediated radicalreaction of 60 fullerene with phosphonate esters affording unprecedentedseparable singly-bonded 60 fullerene dimers. Chem Commun 2011, 47, (21),6111-6113.
12. Wang, G. W.;Miao, T., PalladiumCatalyzed Desulfitative Heck-Type Reaction of Aryl SulfinicAcids with 烯烃 Chem-Eur J 2011, 17, (21), 5787-5790.
13. Wang, G. W.;Liu, T. X.; Jiao, M. Z.; Wang, N.; Zhu, S. E.; Chen, C. B.; Yang, S. F.;Bowles, F. L.; Beavers, C. M.; Olmstead, M. M.; Mercado, B. Q.; Balch, A. L.,The Cycloaddition Reaction of I-h-Sc3N@C-80 with2-Amino-4,5-diisopropoxybenzoic Acid and Isoamyl Nitrite to Produce anOpen-Cage Metallofullerene. Angew Chem Int Edit 2011, 50, (20), 4658-4662.
14. Miao, T.;Wang, G. W., Synthesis of ketones by 钯catalysed desulfitative reactionof arylsulfinic acids with nitriles. Chem Commun 2011, 47, (33), 9501-9503.
15. Liu, T. X.;Li, F. B.; Wang, G. W., Synthesis of 60 Fullerene-Fused Tetrahydronaphthaleneand Indane Derivatives via a Pathway Switched by Aluminum 氯化物 Org Lett2011, 13, (22), 6130-6133.
16. Li, D. D.;Yuan, T. T.; Wang, G. W., Synthesis of isoindolinones via 钯catalyzedC-H activation of N-methoxybenzamides. Chem Commun 2011, 47, (48), 12789-12791.
17. Wang, G. W.;Yuan, T. T., Palladium-Catalyzed Alkoxylation of N-Methoxybenzamides via Directsp(2) C-H Bond Activation. J Org Chem 2010, 75, (2), 476-479.
18. Li, F. B.;You, X.; Wang, G. W., Synthesis of Disubstituted 60 Fullerene-Fused 内酯:Ferric Perchlorate-Promoted Reaction of 60 Fullerene with Malonate Esters. OrgLett 2010, 12, (21), 4896-4899.
19. Li, F. B.;Liu, T. X.; You, X.; Wang, G. W., A Facile Access to 60 Fullerene-Fused1,3-Dioxolanes: Reaction of 60 Fullerene with Aldehydes/Ketones Promoted byFerric Perchlorate. Org Lett 2010, 12, (14), 3258-3261.
20. Zhu, B.;Wang, G. W., 钯Catalyzed Heteroannulation of 60 Fullerene with Anilidesvia C-H Bond Activation. Org Lett 2009, 11, (19), 4334-4337.
21. Wang, G. W.;Zhu, B., A facile access to 60 fullerene-fused delta-内酯: unexpectedreaction pathway of benzenediazonium-2-carboxylates controlled by organicbases. Chem Commun 2009, (13), 1769-1771.
22. Wang, G. W.;Lu, Y. M.; Chen, Z. X., 1,4-Fullerenols C60ArOH: Synthesis andFunctionalization. Org Lett 2009, 11, (7), 1507-1510.
23. Wang, G. W.;Gao, J., Selective Formation of Spiro Dihydrofurans and Cyclopropanes ThroughUnexpected Reaction of Aldehydes with 1,3-Dicarbonyl Compounds. Org Lett 2009,11, (11), 2385-2388.
24. Li, F. B.;Liu, T. X.; Huang, Y. S.; Wang, G. W., Synthesis of Fullerene-Fused 内酯and Fullerenyl Esters: Radical Reaction of 60 Fullerene with Carboxylic AcidsPromoted by 锰(III) 乙酸盐 and 铅(IV) Acetate. J Org Chem 2009, 74,(20), 7743-7749.
25. Wang, G. W.;Dong, Y. W.; Wu, P.; Yuan, T. T.; Shen, Y. B., Unexpected solvent-freecycloadditions of 1,3-cyclohexanediones to 1-(pyridin-2-yl)-enones mediated bymanganese(III) 乙酸盐 in a ball mill. J Org Chem 2008, 73, (18), 7088-7095.
26. Li, F. B.;Liu, T. X.; Wang, G. W., Synthesis of fullerooxazoles: Novel reactions of 60fullerene with nitriles promoted by ferric perchlorate. J Org Chem 2008, 73,(16), 6417-6420.
27. Gao, J.;Wang, G. W., Direct oxidative amidation of aldehydes with anilines undermechanical milling conditions. J Org Chem 2008, 73, (7), 2955-2958.
28. Wu, X. L.;Wang, G. W., Aminochlorination in H₂O: First Bronsted acid-promoted synthesisof vicinal chloramines. J Org Chem 2007, 72, (24), 9398-9401.
29. Wang, G. W.;Li, F. B.; Xu, Y., Novel functionalizations of 60 fullerene-fused 内酯 JOrg Chem 2007, 72, (13), 4774-4778.
30. Wang, G. W.;Li, F. B.; Chen, Z. X.; Wu, P.; Cheng, B.; Xu, Y., Synthesis of 60 fullereneacetals and ketals: Reaction of 60 fullerene with aldehydes/ketones andalkoxides. J Org Chem 2007, 72, (13), 4779-4783.
1997-2006
1. Guan-Wu Wang, Koichi Komatsu,* Yasujiro Murata, and Motoo Shiro, "Synthesis and X-Ray Structure of Dumb-Bell-Shaped C120", Nature 1997, 387, 583-586. (cover title, news reported by C \u0026 EN, news reported by Kyoto Newspaper)
2. Mark S. Meier,* Guan-Wu Wang, Robert C. Haddon, Carolyn Pratt. Brock, Michael A. Lloyd, and John P. Selegue, "Benzyne Adds Across a Closed 5-6 Ring Fusion in C70: Evidence for Bond Delocalization in Fullerenes", J. Am. Chem. Soc. 1998, 120, 2337-2342.
3. Guan-Wu Wang,* Xin-Hao Zhang, Huan Zhan, Qing-Xiang Guo, and Yun-Dong Wu, “Accurate Calculation, Prediction, and Assignment of 3He NMR Chemical Shifts of 氦气3-Encapsulated Fullerenes and Fullerene Derivatives”, J. Org. Chem. 2003, 68, 6732-6738.
4. Guan-Wu Wang, “Fullerene 机械化学”, in Encyclopedia of Nanoscience and Nanotechnology, H. S. Nalwa, Ed., American Scientific Publishers: Stevenson Ranch, Vol. 3, p. 557-565, 2004. (invited book chapter).
5. Ze Zhang, Guan-Wu Wang,* Chun-Bao Miao, Ya-Wei Dong, and YEBing Shen, “固体state Radical Reactions of 1,3-Cyclohexanediones with in situ Generated Imines Mediated by 锰(III) Acetate under Mechanical Milling Conditions”, Chem. Commun. 2004, 1832-1833.
6. Zhong-Xiu Chen, and Guan-Wu Wang,* “One-Pot Sequential Synthesis of Acetoxylated Fullerene Derivatives”, J. Org. Chem. 2005, 70, 2380-2383.
7. Guan-Wu Wang,* Jia-Xing, Li, Yu-Jin Li, and You-Cheng Liu, “Novel Reactions of Fullerene with Amino Acid Esters and 碳 Disulfide”, J. Org. Chem. 2006, 71, 680-684.
8. Guan-Wu Wang,* Fa-Bao Li, Ting-Hu Zhang, “Fullerene-Fused Lactones: 锰(III) 乙酸盐Mediated Synthesis and Novel Reductive Ring Opening”, Org. Lett. 2006, 8, 1355-1358.
9. Guan-Wu Wang,* Hai-Tao Yang, Ping Wu, Chun-Bao Miao, and Yu Xu, “Novel Cycloaddition Reaction of Fullerene with Carbonyl Ylides Generated from Epoxides”, J. Org. Chem. 2006, 71, 4346-4348.
参考资料
王官武教授简介.实验室.2021-12-26