沈增明
沈增明,女,1977年出生于柯桥区,现为上海交通大学化学化工学院教授、博士生导师。2001年至2006年在中科院上海有机化学研究所攻读硕博学位,师从陆熙炎院士。2006年至2008年在多伦多大学化学系进行博士后研究。自2010年起,沈增明在上海交通大学化学化工学院担任副教授,2018年1月起晋升为教授。本科生主要教《有机化学》这门学科,而研究生主要教授《现代有机合成》。研究方向有以下三个:金属催化的新型有机反应研究;金属催化的不对称反应的研究;杂环化合物的研究。
人物履历
教育经历
1997-2001:四川师范大学化学系,学士
2001-2006:中国科学院上海有机化学研究所,硕博(导师:陆熙炎院士)
2006-2008:多伦多大学化学系,博士后
工作经历
2010-2018.1:上海交通大学化学化工学院,副教授,硕士生导师
2018.1-至今:上海交通大学化学化工学院,教授、博士生导师
个人成果
科研项目
铜催化的C—H键官能团化实现交叉偶联反应,国家中华人民共和国国家自然科学基金委员会青年科学基金 .01-2012.12,已结题。
入选2009年度上海市浦江人才计划 2009.7-2011.7,已结题。
惰性C-H键在廉价金属铜催化下的反应性研究,上海交通大学校长机动费研究基金,2011.1-2013.12。
铜催化的C-C键断裂反应的研究,国家自然科学基金面上项目 2013.1-2016.12。
铜催化的C-C键断裂反应的研究,上海市教委创新重点项目 2013.1-2015.12。
代表论文
1. Li, Xiaomeng; Guo, Yunlong; Shen, Zengming* J. Org. Chem. 2018, 83, 2818.
2. Cruz, Faben A.; Zhu, Yamin; (并列一作,按字母顺序排列) Tercenio, Quentin D.; Shen, Zengming*, 越南盾, Vy M.* “Alkyne Hydroheteroarylation: nantioselective Coupling of Indoles and Alkynes via Rh-Hydride Catalysis” J. Am. Chem. Soc. 2017, 139, 10641-10644.
3. Zhu, Yamin; Shen, Zengming* “Copper-Catalyzed Acyloxycyanation of Alkynes with Acetonitrile: Regioselective Construction of Cyclic Acrylonitriles by 6-endo or 5-EXO Cyclization” Adv. Synth. Catal. 2017, 359, 3515.
4. Lu, Wenkui; Xu Hui; Shen Zengming* “Copper-catalyzed aromatic C–H alkoxylation with alcohols under aerobic conditions” Org. Bio摩尔 Chem., 2017, 15, 1261–1267.
5. Yu, Zhengwei; Li, Linyi; Shen, Zengming* “Cu-Catalyzed Cyanation of Aryl Iodides with Acetonitrile as Cyano Source” Chin. J. Org. Chem. 2017, 37, 1273-1277.
6. Zhang Wei; Yang, Shiping; Shen, Zengming* “Copper-Catalyzed Cyanomethylation of Substituted Tetrahydroisoquinolines with Acetonitrile” Adv. Synth. Catal. 2016, 358, 2392– 2397.
7. Zhao, Mengdi; Zhang, Wei; Shen, Zengming* “Cu-Catalyzed Cyanation of Indoles with Acetonitrile as a Cyano source” J. Org. Chem. 2015, 80, 8868.
8. Li, Linyi; Yu, Zhengwei; Shen, Zengming*; “Copper-Catalyzed Aminoxylation of Different Types of Hydrocarbons with TEMPO: A Concise Route to N-Alkoxyamine Derivatives” Adv. Syn. cat 2015, 357, 3495.
9. Zhu, Yamin; Li, Linyi; Shen, Zengming* “Cu-Catalyzed Cyanation of Arylboronic Acids with Acetonitrile: A Dual Role of TEMPO” Chem. Eur. J. 2015, 21, 13246.(Highlighted as a cover.)
10. Zhu, Yamin; Zhao, Mengdi; Lu, Wenkui; Li, Linyi; Shen, Zengming* “Acetonitrile as a Cyanating Reagent: Cu-Catalyzed Cyanation of Arenes” Org. Lett. 2015, 17, 2602. (Highlighted by Synform. See: Synform 2015, 10, A144–A145.)
11. Xu, Hui; Qiao, Xixue; Yang, Shiping; Shen, Zengming* “Cu-Catalyzed Direct Amidation of Aromatic C−H Bonds: An Access to Arylamines” J. Org. Chem. 2014, 79, 4414.
12. Kou, Xuezhen; Zhao, Mengdi; Qiao, Xixue; Zhu, Yamin; Tong, Xiaofeng; Shen, Zengming* “Copper-Catalyzed Aromatic C-H Bond Cyanation by C-CN Bond Cleavage of Inert Acetonitrile” Chem. Eur. J. 2013, 19, 16880-16886. (Highlighted as a frontispiece.)
13. Mo Song, Zhu Yamin, Shen Zengmging*, “Copper-catalyzed aromatic C–H bond halogenation with lithium halides under aerobic conditions” Org. Bio摩尔 Chem. 2013, 11, 2756-2760. (Hot Paper, highlighted as a cover.)
14. Kou Xuezhen, Fan Jiajun, Tong Xiaofeng, Shen Zengming*, “Recent Progress in the Research of Transition Metal-Catalyzed C-CN Bond Cleavage” Chin. J. Org. Chem. 2013, 33, 1407-1422.
15. Shen, Zengming*; Ni, Zhenjie; Mo, Song; Wang, Jing; Zhu, Yamin; “PalladiumCatalyzed Intramolecular Decarboxylative Coupling of Arene Carboxylic Acids/Esters with Aryl Bromides” Chem. Eur. J. 2012, 18, 4859-4865.
16. Wang, Ruiping; Mo, Song; Lu, Yongzhong; Shen, Zengming*; “Domino Sonogashira Coupling/Cyclization Reaction Catalyzed by Copper and ppb Levels of Palladium: A Concise Route to Indoles and Benzo[b]furans” Adv. Synth. Catal. 2011, 353, 713-718.
17. Lu, Yongzhong; Wang, Ruiping; Qiao, Xixue; Shen, Zengming*; “Copper-Catalyzed Aromatic C–H Bond Halogenation Using Lithium Halides as Halogenating Reagents” Synlett, 2011, 1038. (the special issue of Synlett dedicated to Professors Xiyan Lu and Li-Xin Dai).
18. Shen, Zengming; Dornan, Peter K.; Khan, Hasan A; Woo, Tom; Dong, Vy M. “Mechanistic Insights into the Rhodium-Catalyzed Intramolecular Ketone Hydroacylation” J. Am. Chem. Soc. 2009, 131, 1077-1091.
19. Shen, Zengming; Dong, Vy M. “Benzofurans Prepared by C-H Bond Functionalization with Acylsilanes” Angew. Chem. Int. Ed. 2009, 48, 784-786. (For a highlight, see: Synfacts, 2009, 4, 409)
20. Shen, Zengming; Khan, Hasan A.; Dong, Vy M. “Rh-Catalyzed Carbonyl Hydroacylation: An Enantioselective Approach to Lactones” J. Am. Chem. Soc. 2008, 130, 2916-2917.
· (See the highlight in 化学 World featuring this work: James Mitchell Crow, "Rhodium fast tracks route to lactones." Editorial Board of SYNFACTS selects this article as the Synfact of the month, see: Synfacts, 2008, 5, 485).
21. Shen, Zengming; Lu, Xiyan; “Cupric Halide-Mediated Intramolecular Halocyclization of N-Electron-Withdrawing Group-Substituted 2-Alkynylanilines for the Synthesis of 3-Haloindoles” Adv. Synth. Catal. 2009, 351, 3107-3112.
荣誉奖励
1、2006年获“中国科学院大学优秀毕业生”称号
2、2009年获“上海市浦江人才计划”
3、2010年获上海交通大学“SMC-晨星青年学者奖励计划”优秀青年教师B类
4、2013年度三年聘期工作考核“优秀”
5、2016年和2017年教职工年度述职考核“优秀”
6、首届上海交通大学“教书育人奖”提名奖(2017)
7、第二届上海高校青年教师教学竞赛“二等奖”(2016)
8、上海交通大学首届青年教师教学竞赛“一等奖”(2016)
9、上海交通大学教学能手称号(2016)
10、上海交通大学优秀教师“二等奖”(2016)
11、上海交通大学“SMC-晨星青年学者奖励计划”优秀青年教师A类和B类(2017/2010)
参考资料
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